The original battery is 8 months old. They are both 110ah. I was just wondering if the readout would stay at 13.6 even if both batteries are fully charged or if it shows the total voltage stored. i.e, 1 Battery 13.6, 2 27.2, 3 39.8 etc.
As has been said, it is down to how connected. There is no such thing as a "voltage stored". Your 12V battery is made up of 6 cells each 2V each connected in series so you get 12V at the terminals. If you were to connect the 2nd battery in series (you shouldn't!), then you would have in effect 12 2V cells in series giving 24V. In parallel, the group of 6 cells in battery 1 are connected across the group of 6 cells in battery 2.
Adding another battery you are adding Power (WattHours).
If you connect two in Parallel (+ve to +ve, -ve to -ve), you are doubling Ah's, but keeping voltage the same. If you are connecting two in Series, you are doubling Voltage, but keeping Ahs the same. Identical to how you work out Solar Panel connections.
to do the sums (and using 100Ah instead of 110Ah to make it Maths easier)
100Ah battery at 12V = 1200Wh of power
Adding a second 100Ah battery... In series, (12V + 12V) * 100Ah = 2400Wh; In parallel, 12V * (100Ah + 100Ah) = 2400Wh. Same result, just different way to get there.