Not sure if the power of the AC charger will matter that much if it is a multi-stage unit? (mine is a 120A unit).
I found the key to having the (30A) MPPT working when it was light instead of the Mains Charger was to have the voltage set slightly higher than the AC Charger (so my AC Charger is set at 14.1V and my MPPT is 14.2V (my batteries prefer a lower CV voltage than the typical AGM battery))
I would expect if you set the MPPT CV voltage to below the float of the Mains (taking account of any temp/voltage compensation) the MPPT will either never go to bulk and/or absorption, or will go through those stages really fast? (I said mine skipped from bulk to float? It is possible it DID go to an absorption phase but for such a short time the monitoring system didn't pick it up (it samples every minute))
I would normally try some different settings with my kit to see if I could help investigate further, but about to head off in a couple of days for a week or so, so need to start my trip off with full batteries.