saxonborg
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Thank you for your explanation, still trying to get my head around the detail, for info my Victron controller is the smart solar 100/20 unit, there are three sets of connections, solar panel connections, battery connections and load connections, I still need to re-read your posts and it will eventually sink in.Just to answer the Solar Question:
The Majority of the Victron MOT Solar Controllers have one pair of inputs - for the Panels to feed into; and one pair of outputs - to connect to the Leisure Battery.
As far as 'engine' charging goes, the problem with just relying on the alternator to do the charging is that it will rarely be at a voltage level that will allow for full battery charging - either Starter OR Leisure. It is good practice (although rarely done) to periodically connect the starter battery to a good mains charger to give it a proper full charge. Does it matter? usually won't be noticable, but doing that will maintain the battery better.
A B2B Charger takes care of 'proper' Lesiure Battery charging via alternator as they will boost the voltage upto 14.4V or whatever. This is the best option for Split-Charging where funds allow (reckon on around £200 more for a B2B over a basic relay).
If you have a good Solar Controller with a multi-stage charging profile (which the Victron does, of course), then that controller can carry on where the alternator left off the charging and finish the job off, as it were, so your Leisure Batteries will be treated well probably, even if you have a basic Relay rather than a B2B.
If you do have a relay system that is voltage switched rather than engine/ignition switched and is bi-directional sensing, then you will find that the Solar Controller will also start charging the Starter Battery once the Leisure Batteries are at a reasonable charge level - when this happens, your intelligent Victron Solar Controller will give your Starter battery a decent full charge as well. This is a handy bonus of the basic VSR system.
I don't know much about the EBL99 so don't know what that can or can't do in this respect.
Something that could be worth considering as you said you are replacing the Starter Battery ... maybe replace with the same battery technology as the Leisure Batteries if appropriate so the charging profile of the Victron MPPT Controller matches both battery sets for optimum charging. When I replaced my Starter Battery last year I actually used exactly the same model as I had in my Leisure Battery Bank for this reason so when the VSR came on, all batteries got charge profile they needed.
If you don't have a setup where the Solar will charge the Starter Batterty, then a trickle charge device such as a Battery Master can be fitted.