BMS usually stands for Battery Management System - generally relates to something fitted to a Lithium Battery and manages the battery, ensuring when the battery will charge, manages over-current, this kind of thing. Not an actual charger device
B2B stands for Battery to Battery and is a mechanism to charge a Leisure Battery from the alternator in a managed way using a multi-stage smart DC-DC charger.
Most advanced form of a split-charger.
The more basic split-charger system would be a relay, that just closes when engine runs or voltage hits a certain level (depending on relay type).
Relay is a lot cheaper than B2B. B2B is better than Relay.
If this is for the motorhome in your Avatar you must have something fitted at the moment and if you want to improve it you almost certainly need to disable what is in place.